As I understand it, the chemistry of Li-PO cells are the same as Li-Ion; in fact, the voltage is identical. The main difference is Li-PO has a flexible (polymer) housing wheras Li-Ion has a rigid (metal) housing. Li-PO cells can therefore be almost any size and shape, although most I've seen are still roughly rectangular. The polymer housing does mean however one must use more care when charging a Li-PO battery.
The individual cells are best charged using a "balancing" charger, which simultaneously charges the cells in a battery in parallel. While you can charge cells in series, and some chargers do it this way, it is not recommended since a single cell could overcharge which could lead to bad consequences (fire, explosions, etc.). BTW, some folks advocate using balancing chargers for LI-Ion batteries as well. It is further recommended that one not charge a Li-PO battery unattended. Model airplane users typically remove the battery from the airplane to charge it and some use a "charging bag" which is intended to contain any shrapnel etc.
I'm not sure how credible the doomsday scenarios are, but that's what I've read. (There's a member at "that other forum" who is a strong proponent of the doomsday stuff.
) I figure a Stainz boiler is at least as strong as any charging bag
and I use a balancing charger which I believe mitigates the hazards.
Anyway, I'm off to push the envelope (my own envelope, at least).